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Product Design

Cigarette Design

Date: 1900
Length: 35 pages
400132742-400132776 Exhibit 11
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youth 3194

Abstract

Detailed discussion of cigarette paper, filter, and tip ventilation, and their influence on smoke delivery. Notes the addition of chalk and salt additives to cigarette paper to control ash formation and modify burn rates; and the modification of paper permeability (measured in CORESTA units), either through paper porosity or the addition of electrostatic or mechanical holes, to reduce tobacco burnt during each puff and alter burn rate and puff count. Describes how filter may be used to alter the character of smoke by removing smoke constituents either in the particulate or vapor phase of smoke. Discusses measurement of the effectiveness of the filter, or filtration efficiency (FE). Describes tip ventilation, the process of introducing holes in the cigarete wrapper to allow air dilution of mainstream smoke thereby reducing delivery. Also describes in detail the formation of "Cigarette Smoke", including combustion process, generation of smoke, methods of measuring and reporting components of smoke, delivery of nicotine and other components, and tobacco grades and blending practices influencing or controlling component variability. Identifies filter pressure drop as the most important product factor influencing delivery variability of non-ventilated products. Ventilation is shown to be critical in development of low-delivery cigarette.

Fields

Rank
1
Hypothesis
FTC machine testing and ratings
Design changes to achieve altered FTC smoke machine tar and nicotine ratings, with or without measured changes in human intake.
Low-yield cigarettes
Modification of low yield products to assure that adequate levels of nicotine delivery are maintained, and effects of yield changes on toxicity and dependence.
Mainstream constituent yields
Modification of selected mainstream smoke constituents in response to health concerns.
Nicotine transport, transfer, and uptake
Design changes which alter nicotine delivery or effect how the product causes and maintains dependence, including transfer of nicotine from tobacco to smoke, and uptake into the body.
Use of additives
Modification of tobacco products through use of additives and measuring effects on dependence, behavior, and toxicity.
Use of filters, paper, and ventilation
Modification of tobacco products through use of filters, paper, and ventilation, and measuring effects on dependence, behavior, and toxicity.
Use of tobacco processing/ blends
Modification of tobacco products through changes in tobacco processing and use of blends, and measuring effects on dependence, behavior, and toxicity.
Elasticity and Product Control
Design Basics
Keyword
Free nicotine (Unprotonated or unionized nicotine)
Impact (Throat grab)
Smoke pH
Acidity/ baseness, scale from 0-14, 7 neutral
Pyrolysis
Respiratory system
Acidity (Low pH)
Alkalinity (High pH, Basic)
Bullseye effect
Exhaled smoke
Additive
Chalk
Disodium hydrogen phosphate
Potassium citrate
Salts
Sodium citrate
Smoke Constituent
Carbon monoxide
Total particulate matter
Gas phase constituents
Particulate phase delivery
Total particulate matter
Dry TPM
Dry TPM
Total particulate matter
Total nicotine alkaloids (TNAs)
Design Component
Cellulose acetate filter (CA filter, Conventional filter)
Air dilution
Electrostatic perforation 1 (EP)
Method for manufacturing @filter_ventilation to alter @air_dilution
Flax paper (Flax wrapper)
Hemp
Natural paper permeability 2
Paper filter
Plug wrap (Plugwrap)
Tipping paper
Tobacco grade
Viscose filters
Woodpulp fiber
Pressure drop (PD, Resistance to draw (RTD), Flow rate or Draft)
Coal
Combustion
Combustion zone
Filter efficiency 3 (FE)
Ash formation
Static burn rate 4
Temperature
Filter ventilation (Filter vents, air vents)
Named Organization
Hauni
Technology/Method
Cambridge filter pad
Electrostatic spark perforator
Hauni tipping attachments
CORESTA
Subject
aerosol (technology)
Burn Rate (Design)
Smoke Delivery/Transport (Measures)
Filters (Design)
Paper (Design)
Particle Size (Technology)
pH Manipulation (Technology)
Puff Count (Measures)
Smoke Constituents
Smoke Nicotine (Measures)
Smoke pH (Measures)
Sugars (Additives)
Glucose/Invert Sugar/Fructose/Sucrose
T/N Ratios (Measures)
Tobacco Weight (Design)
acids (additives)

Annotations

1. Electrostatic perforation Design Component
  • Synonyms:

    EP

2. Natural paper permeability Design Component
  • Synonyms:

    NP

3. Filter efficiency Design Component
  • Synonyms:

    FE

4. Static burn rate Design Component
  • Synonyms:

    SBR

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Page 1: 3194
BAT Co L~ - M*-','.~'~so~.a To~,~cco Lrr~¢ario.~. ~
Page 2: 3194
CIGARETTE DESIGN - A~( OVERVieW I~TRODUCTIOt; A cigarette can con'~enien~ly be Cescribed aS a four component i. 2. 3. 4. Cigarette paper Filter Tip ventilation Blend. In order to ~eet the defined market brief, these are the four components which can be modified. In this paper we will consider what charges can be made in the first three components and the effects these changes have on the deliveries. It is extremely important to appreciate how these four components may be brought together to end up with a product or products which are likely to satisfy both the subjective and the objective requirements given in the brief. I. CIGARETTE PAPER Cigarette paper is not just simply the white wrapping material used to hold the tobacco in the cigarette. By virtue of its physical end chemical characteristics, it has a fundamental influence upon the quality, the appearance and the ~o~bustlon of the cigarette~. Most papers ire based on ~ax, hemp and woodpulp fibres and contain 20-30% chalk, The chalk serves to increase the opacity of the papers end to cause formation of an attractive white paper ash. Along with the chalk, salts are added to the paper for three main reasons, viz: e) To minimise the tendency of cigarette paper to disco|our during storage:
Page 3: 3194
/2 b) TO control ash formation. c} TO modify the burn rate of the cigarette which in turn can infZuence the deliveries tca limited extent. This wit] be c:nsidered in more detail later in the paper. The pr:perty of the c~ret~e paper that has the ~ost significant effect on deliveries is its PERMEA.~ILITY which is usually specified in CO~E~TA Units. The CZRESTA Unit is defined as the flo'~ of air in cm3/min through a sample O~ ~aper Icm2 in area when a pressure difference of 10c~ water is applie: across the paper. The more porous the pa~er is, the higher will be the air permeability as measured in CORESTA Units. The desired level of air permeability for the paper may be achieved in two ways: I. By making the paper inherent~ porous during its manufacture, This is normally referred to as the Natural Permeability {NP) end the normal commercially available papers cover a permeabilltx range from B to 200 CORESTA Units. By passing an inherently porous paper through a secondary process where devices puncture, burn or cut holes in the paper. ~hese holes tend to be considerably larger than the pores of the NP papers. The most tone.on method of introducing holes is to use an Electrostatic Spark Perforator and hence these papers are referred to as [P papers. One general effect of increasing the ~ermeabi~ity of ~be paper (NP and/or EP) is to reduce the weight Of tobacco burnt during the puff. 7he reason for this being that as a fixed volume of air is drawn through the cigarette, higher permeability paper will let in more air through the paper envelope (dilution) and thus a lower volume of air wtl~ pass
Page 4: 3194
tb-ougn the burninq coal. The effects of increasin~ permeability • a/ be sum~arised as follows: I. St~:ic burn rate (SBR) increases as we increase NP from very low tz about 70 C.U. and thereafter the chanqes are small. ~ possihl~ reason being that as NP is increased, more oxygen becnmes avai:ab~e fz, efficient combustion but at around 70 C.U. enouoh oxygen available and hence there is very limited effect thereafter. 2. i-:roducing EP to a base paper does not alter the static burn Increasing NP UD to about 70 C.U. results in reduced puff number because although a lower weight of tobacco is consumed during the puffs, the weight of tobacco consumed between puffs increases more rapidly as illustrated in the Slide. Beyond this level, there is no change in SBR but the weight of tobacco consumed during the puff reduces and hence a sllg~t increase in puff number is observed. BAT Co LTD - Mixx so r. Tobacco Lrno, 'rio.,,-
Page 5: 3194
[ntroducinq 6P does not a)ter the 58R but reduces the wefghc of tobacco consumed pe. buff and hence ~ncre~ses thp buff number. Increasing NP reduces deliveries with a greater reduction being observed for CO, followed by tar and nicotine. Thus, tar to nicotine ratio will reduce. EFPECT OF CHANGING THE NATURAL PERMEABILITY OF CIGARETTE PAPER ON SMOKE ~ELIVERtES BAT Co LTD - M~.~o~..~, To,~,~cco Lmo,~'ndx-
Page 6: 3194
Similar effects occur from increasing E~ but the effects a~e lowe~ tbam for NP beCause whereas NP affects both SmR amd level of dilution EP only affects the level of dilution. EFFECT OF ELECTROSTATIC FE~,FORATION OF CIGARETTE PAPER ON SMOKE DELIVERIES PERMEABILITY (CORESTA UNITS) Turning now to the additives, the followlng chemicals in the range 0.5-3% are in common use: ~onoan~onium Phosphate is added as an ash conditioner and only slightly increases the burn rate of the cigarette compared to oaper with no additives which are the slowest burning papers. ~isodium H~dro~en Phosohate increases the burn rate of the clqarette relative to that found from using the monoar~aunium phosohate additive. Sodium and Potassium Citrates are most commonly used as burn accelerators. This reduces tar delivery per cigarette by reducing the puff number as a result of more tobacco being consumed in between puffs. However, tar delivery per puff should not be slgnlficantly affected. BAT Co - M xx soT., Tobacco Lmo, Tiox
Page 7: 3194
/6 phosphate ~disodium hydrnq~n Ohosnrate ~¢itr!~ - fast~st hur~inl. 2. FILTE: to divide filters intn twn grm, os - thnse which mainly remove smnk= vapour phase. A rigid sun-division is not possible since m~ny smnk~ constituents (semi-volati]es) are ~r~sent in both ohases and it is possible to design filters which are effective for both phases of smnke. In this p~per we will concentrate on filters for the ~articulate ~ost cigarette filters which remove particulate phase consist of fibrous or filamentary materials which capture the smoke particles they pass through. Over gO~ of the filters used conlnercially are cellulose acetate, with the remainder being paper and viscose. Further, much of the paper used goes into dual filters with the paper section next to the tobacco and the acetate section st the mouth end. The effectiveness of a filter is measured by its filtration efficiency (FE). FILTRATION EFFICIENCY (,FE)
Page 8: 3194
/ 7 * ~o0 Various filtration s:udies have shown that, in general, fi]:ra~ion efficienciss are i~imately related to the pressure drops in filtration e~ficiencies. Thus, for extols, increasing the length will increase both preSSure drop an¢ FE. However, the absolute increase in oressure drop and FE will n~t be identical. This is illustrated below: EFFECT OF LENGTH ON PRESSURE DROP AND FE BAT Co LrD - Mz.xx~soT.~, To~.o l ~,~.~4,~,-
Page 9: 3194
/9 FILTRATION EFFICIENCY - T~M & NICOTIHE 25ram CA FILTE~ Some brands also use a dual filte- which consists of a length of paper filter next to the tobacco (referred to as the 'T' section), followed by a length of cellulose acetate filter at the mouth end (or the 'M' section). This filter cosines the advantages of high]y effective paper filters with the acceptable white end appearance of cellulose acetate filters. The filtration efficiency of each section can be adjusted to particular requir~ents and following the logic i11ustrated in Slide 6 it can be shown that the combined efficiency is: FEdual • FE paper + (100 - FEpaper) FECA 100 where FE is the percentage filtration efficiency for the particular section used in the dual filter. 3. TiP VEHTILATIDN Ventilation, in simple terms, is the process of Introducl~g holes in the wrapper of a cigarette. The holes allow air to enter the mainstream smoke when the cigarette is smoked. The air thus entering BAT Co - MixxEso'r. To . .co
Page 10: 3194
110 the cigarette is not used to burn the tobacco, Hence, less tobacco w111 be burnt during each puff and the delivery of smoke reduced. Tip ventilation, ~ore specifically, is the amount of air entering through the tipping/plugwrap combination and is normaR]¢ expressed as a percentage O~ the total volume drawn through the cigarette. The relationship between bercentage tip ventilation and delivery reduc:ion for the nx)st common s~oke constituents measured is: OVERALL~ 60 40 20 VENTII-~TION ('~) -- UNLIT CIGAR=TTES The line for PHWNF is an approximate 1:1 relationshio, i.e. percentage tip ventilation approxfmately equals percentage reduction of PMWNF. For nicotine the reduction is less at any oartlculer level of ventilation relative to tar end therefore as tip ventilation Is increased the tar to nicotine ratlo reduces. The reduction for CO |s greater than BAT Co L'r

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