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,r 4 . U.S. DEPARTMENT OF LABOR Occupationai Safety and Health Administration OM9 Ho, «•Rtit7 MATEIIAL SAFETY DATA SHEET Required under USQL Safoty and Health Re9ulationt for Ship'Repairin9, Shipbuilding, and Shipbrcaking (29 CFR 1915, 1916, 1917) ' SECTION i MANUFACTURER'S NAME DEGESCH America, Inc. ~ Inor anic - Meta1 Phosphide Mg3 ~+ Water - PIi.) gas , EMERGENCY TELEPHONE NO. 800-424-9300 CHEMICAL NAME AND iYNONYMS ' rTRAOE NAME AND LYNONYMi ~,Manesium Phosphide (releases hydrogen phosphide PH hosphine) Magtoxin©s Fumi-Cel® CH ICAL FAMILY FQ$ M Ptitmi-Stripa ADDRESS f um6er, Street, rrv, S/aft,.WZ1FZ`odtl _p . 0. Box 116, Weyers Cave, Virginia 24486 SECTION !1 • HAZARDOUS INGREDIENTS PAINT:, PRESERVATiVEi, 0 SOLVENTi % T Unitid LV ALLOYS ANO METALIIC GOAT1NRZ !G f~~Vs' PIGMENTS ~. ~ 0 111 fE vfTAL .-.... CATALYST . ~ VEHICLE METALLIC COATINGS SOLVENTS FILLER METAL PI:US COATING OR CORE FLUX ADDITIVES OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % (Unrtt) Ma nesium Phos hide (releases 33 PH per Fumi-Cel or 528 TLV/TWA PH 0 MgP CAS l/ 12057-74-8 TLV/STEL PH 1 IDLH PH 200 m SECTION III - PHYSICAL DATA BOILING POINT 87.4 ° SPECIFIC GRAVITY (H=O•i) ~ ' VAPOR PRESSURE (mm Hg,) PERCENT, VOLATILE. BY VOLUME (%) --- VAPOR DENSITY (AIR•1) 1~ 1H4 EVAPORATION RATE --- ( 1) SOLUBILITY IN WATER ery slig t 6 APPEARANCE AND ODOR PH., is a colorless gas with a arlic-like or carbide odor SECTiON IV - FIRE AND EXPLOSION HAZARD DATA ® FLASH POINT (M9IAOtl uSeC) ° ° FLAMMABLE LIMITS Lei ~ C/212 100 F lower 1.79 vol: % - EXTINGUISHING MEDIA Carbon Dioxide (CO ) Dr Chemical ExtinQ ishe No Wate SPECIAL FIRE FIGHTING PROCEDUaES Do not use water Uf.USUAL FIRE AND EXPLOSION HAZARDS Ma =nesium hos hida ro u Do not open product in an explosive atmosphere. Open onl out of doors or in we I venti ate area. PAGE (1) (Continu.d on rrvorw side) I form Approved Form OSHA•20 ~

SECTION V• HEALTH HAZARD DATA fHNf5HOL0 4.IM1T VALUE 0.3 ppm/TWA 1.0 ppm/STEL ~ EFPF.CTSOF OVEREKNOSURE _ May cause poisoning_if inhaled - fatigue, nausea, diarrhea, chest pains, ~ . __j cyanosis, dizziness, ataxia EMERGENCY AND PIRST AI PROCED RES • Inhalation: ~resh aYr, keep victim warm, immobilize, r-ontact physician immediately. In severe cases - artificial respiration; oxygen' SECTION VI • REACTIVITY DATA STAOILITY (UNSTAeLE CONOITION; TO AVOIC` contact with liquid water STABLE xx INCOMPATA8ILITY (, orr.rc i~U o"(1; 1 Water, Oxidizing Agents HAZARDOUS DECOMPOSITION PRODUCTS PH HAZARDOUS MAY OCCUR CONO/TIONS TO AVOID POLYMERIZATION WILL NOT OCCUR XX SECTION VII • SPILL OR LEAK PROCEDURES STEPS TO OE TAKEN IN CASE MATERIAL IS RELEAS£C) OR SPILLED The toxic gas PH3 is release W en Fumi-Cel, Fumi-Strip or Magtoxin is exposed to atmospheric moisture. Protect damaged , containers from water and store in a well ventilated area. Broken cases should be opened out of doors. Contact distributor immediately. WASTE DISPOSAL METHQO Spent Fumi-Cel, Fumi-Strips and Magtoxin may be disposed of by burial or incineration' where approved by local regulations. Products may be deactivated prior to disposal b either total immersion in plain water for 24 hrs. or by storing in open air in a e d wire baske fo several da s or more. SECTION Vf {I - SPECIAL PROTECTION INFORMATION RCSPiRATORY PROTECTION (,j'npNfI, 1YnC/ A roved full face gas mask with PH canister must be available at the fumigation in VENTILATION LOCAL EXHAUST SPECIAL case o an emergenc . hrou h draft is sufficient MF.CHANICAL (CifNC1GI) OTHER PROTECTIVE GLOVES I EYG PROTECTION none .r.otton - used for handling Fumi-Cel, Fumi-Strip and Ma toxin I OTHER PROTECTIVE EQUIPMENT ~ I none ~ SECTION IX • SPECIAL PRECAUTIONS ' N PRECAUTIONS TO BE TAKEN IN HANOLING AND STORINC No special precautions. Keep out of ,~'~, reach of unauthorized personnel. Keep away from liquid water. -- ~-~ OTHER PRECAUTIONS Restricted Use Pesticide PAGE (2) cro ~~~.tto F+xm OSHA•20 Rw. M.y 72