Jump to:

Product Design

A Study of the Puff-by-Puff Delivery of Menthol and Nicotine in Cigarette Smoke and the Effects of Air Dilution on Delivery

Date: 23 Oct 1980
Length: 21 pages
00783792-3812
Jump To Images
snapshot_lor 00783792-00783812

Abstract

Reports a simple extraction method for the simultaneous measurement of nicotine and menthol. Says this method is used to study the effects of air dilution on puff-by-puff deliveries of nicotine and menthol. Finds increased air dilution enriches the nicotine content of tar more than menthol and this procedure is useful for analyzing cigarette filler.

Fields

Author
Shoffner, R.A.
Recipient
Ireland, Mary Sue (Lor, Product Composition Chemist, 1965)
Minneme, H. J.
Supervisor of
Schultz, Frederick J., Ph.D. (VP of Lorillard, Inc. '89-95)
Tucker, Charles. L., Jr. (Lor, Product Development Manager, 1979-1983)
Hypothesis
Elasticity and Product Control
FTC machine testing and ratings
Design changes to achieve altered FTC smoke machine tar and nicotine ratings, with or without measured changes in human intake.
Low-yield cigarettes
Modification of low yield products to assure that adequate levels of nicotine delivery are maintained, and effects of yield changes on toxicity and dependence.
Nicotine transport, transfer, and uptake
Design changes which alter nicotine delivery or effect how the product causes and maintains dependence, including transfer of nicotine from tobacco to smoke, and uptake into the body.
Use of additives
Modification of tobacco products through use of additives and measuring effects on dependence, behavior, and toxicity.
Keyword
Menthol delivery (Smoke menthol, menthol yield)
Per puff delivery
Per puff tar, per puff nicotine, and per puff CO
Puff parameters
Total particulate matter (TPM or Tar)
Additive
Menthol
Triacetin
Smoke Constituent
Anethole
Menthol
Neophytadine
Nicotine
Total particulate matter
Design Component
Air dilution
Perforated tipping paper
Pressure drop (PD, Resistance to draw (RTD), Flow rate or Draft)
Tipping paper
Named Organization
Filtrona
Hewlett Packard
Lorillard Tobacco Co. (American cigarette manufacturer)
American cigarette manufacturer; makes Kent, MaxSatin, Newport, Old Gold, Style, and True cigarettes.
Technology/Method
Binary organic solvent system
Cambridge filter pad
Direct extraction
Filtrona 12-port smoking machine
Gas chromatography
GC/FT-IR
GC/MS
Brand
Carlton (ATC)
Doral (RJR)
Golden Lights
Kool (BW (1933-2003)/RJR (2003-present))
First Menthol cigarette line, released in 1933. Premium priced brand.
Merit (PM)
Newport (Lorillard)
Salem (RJR)
Triumph
True (Lor)
Subject
Menthol (Additives)
Puff Count (Measures)
Smoke Delivery/Transport (Measures)
Smoke Nicotine (Measures)
Test/Smoke Machine (Testing)
Ventilation (Design)

Document Images

Text Control

Highlight Text:

OCR Text Alignment:

Image Control

Image Rotation:

Image Size:

Page 11: ugn61e00 Log in for more options!
'TABLE 7 - AIR DILUTIONvs. YIELD REDUCTION 00783802 Pressure % Air - % Yield Redu-ct}on_ - Ti~~- in_ PapEr - - ~ Drop__ __ Dilution Tar_ __ Menthol N~.EOtln€ ~ . - Non Porous 122 0 0 0 0 1 Line Perf. 103 2~0 12.4 10.5 4.8 3 Line Perf. 94 30 31.4 26.9 13.8 6 Line Perf. 90 40 40.1 34.3 20.0 9 Line Perf. 83 50 52.1 44.8 44.1
Page 12: ugn61e00 Log in for more options!
FIGURE 1. T E MI'F 1 170 ' 17B, T I M'~E 1 00.0 1't1J TER.1:-~ 2501 5',, FID RLE;::' TEMP TEMP 2 t•. 0' o 2 ; a s; CG w E H th1 RX 20!11. , C'H T SRn 0 . E. 22" RT T M 2't. 12 FIh wGei!L +F: SL F SE N'S Ei. sFi Hl".;EN'. R'E_J F L OV1' tyl a. FLOW E 13 OPT. H 13 2'. 5 FiTTH'; ;?'-fi 2'. 5 F;REw F"E-i, 16. ..~-~, S'T Or Helium Flow R:ate - Air Flow Rat-e - Hydlroqen Flow Rate - 33 ml/min 2'S0 mS:/mim 4!0 ml/'min
Page 13: ugn61e00 Log in for more options!
2,22 Menthol 4.61 Anethole , ~ 5.53 Nieotine - - - - - 6.49 Ne$pMytadiene \
Page 14: ugn61e00 Log in for more options!
:ij i It ;III t I ~L:I jr rl' j i~j rltl {{ L I l l'' '1 2 1 l +' t t ~l_{i l iL ' r r" i~' Il Q t ~ 11i ~~~. Il' i tl 1 l+f~ r' 11 1, ~ I~ }it, t . . ift, 00 / 38% . lt t 1 ~I,! l " I t 1 , I~ r 1 ,t' d 0 ~ ~ I ~ ~ ~ ~ ~ i(. 7 ~ 7 ' . I ' Tj i L. ~ t t ~ t 1 H i tt ~1 I i i t 1 ; a ~ k I i I 1 t ~ [ L ~ 1_ ~ : f t L i i M oz l ~ a W L 7; ti ~ , i i: I II , I_ l ~ ~ i I --i~ j ~ I - 1 , - . W tD W : , w l ~t :, : EL .:i r; ;llL }1' „ I tt I $ l ;: N Pq. i' . i , ; t ~ t i li I L I L . -~.. _ w t . , t , ' , t ~~±~ : -~ ! ~ ; . i : T; t t t ~ ~ ~ ~ ~pl - - r-- 1 (r1t l' l l i i I ;t' lt r' r i+ 1 t1 j r r t tr !l 1; ~1 t . t.l ! l y . frl I' ( g i ~ } _ ii I •I r t : 1~ { ~ I l i i fi. II' ( t ; I I I i I - 1 I j j t t t, l 1' ! L di IL 11 (Il: I L ~ I r~ ~ 1 a W) 70HaLN3W ,a h 0!-NOPSY Y313MIIN35 3NI Ol 01 Y Ol 3YYNOT ~!,~' ; t"'Ay1'~J ~M"11^p NUi,vucw,ao u a,rti~u ~,ann,n jti~Tq~r ~~ +;~ ~ ~ ~
Page 15: ugn61e00 Log in for more options!
r t 1;JJ ~,{{l , '.,' ~, i , t ~ fl f I T~1T- ~ 777 ; 1 ' ;i ro I ^i: +1 - =1 1 0 0 1 I ! , , 9QeEQ4Q0 ! 1 I I I 1 1 -p 0 ~ , h 1 a 1 f I ~- . .., ,...y ..._. , CowoHdiijrt f ,a S'. ~F 4 y7 &H,tiWac CoNrAr7ts !. . . ~ Vm U$ A " . . - -¢4W n. . . - . U <GuN+~.ti~4wYwk (.,f „! . SOUAAE 10 !l 10 T0 TNE CENTII1ETEt ASa0u-c0 ME1lIT-NOL CA9) ~ $ 0
Page 16: ugn61e00 Log in for more options!
,..; „ ~~...~.- =( j ~-- 1. 0 0 0 ~ ...,-- ~- - 1 -•-- . ~ _.. ._ _... _ . . _ _ __ _ ..,. 1 1 r=- t -~ ::i ~ ~: L t ( } I , - - -~# - - - --- ._ L -- ~ - ---~-- -- =~- -- -- --- _. ._-- --_ __ . -- , . . . ..~ -- -- --~ ~ -- - -- -- ---- - - - t _ r:-- - : - MFh/IrAer L=6mlr _~` --- _~-# - --= -- -- : ' -^ - .. #:-- ---~ -_~ -=- f== ------ -- r -_ ~.- -- -- --_--- - } t , r r - - - r=1 c= i ::: _: 77 _ ~#. -i _ _ - - _ = r== -- - -:=r_-._ - -- - - 0 0 0 0 0 : #'._.. . . r. ` f : Hr .,. E. . t7-- 0 0 0 0 0 0 ~-~-- -~. t { /_-- i - Lr -t t I r=: t I r r E 1 .. 1 _L= 1 c,ocVrwL4007 a i r E a T~R1~6 :i~..l.:. :. l ::.;.---i~---- t ~ .. T-' r._.. ~ i i .:I I .#:.. _. a ;.a ,~, .,.. PUFF N'ufi+BSIR ~+btDc~!r1. : ~ss»r ~no
Page 17: ugn61e00 Log in for more options!
0 { I I i I t { I r 1 i 1 i t I i! 'r~ '1 ll t 1 liT, t t i 0 { t!~ 4 c 1 l I r 6 J 1 ~ { 'itI 1 {i >I I 1 a- , _ j.... { 1 1'I Ili i 1 't' I v~:nr., r y 09 11D6 SY 1)13NI1H39 191 Ol Ol X Ol 31YDDi A."X +*'N NOI tV147dI~tiZ) s~ rrtNOO 3"vM [H3 +V,/ Nava€; ~ t{t 4 n t
Page 18: ugn61e00 Log in for more options!
r VI u CHANGE IN DELIVERY WITH INCREASINGIAIR DILU'TION. i 70 20~ 30 40~, 5101, 60 % Air Di1 ution 70 80 _ . . ....~..~~..~~ . _._~~. ~ .. .. ._.w,...
Page 19: ugn61e00 Log in for more options!
- --_- -_I_-- -_ - --r - -- - - _ - -- ;- ~ - ~ ~ -- _ 7 7 ~~. - = r -t t ;: E-: { } i-: =~_ _::~-: - ~-- -
Page 20: ugn61e00 Log in for more options!
D. ~ 0 L - `FIGURE t.-- _-PUFF-BY-PUFF' laELIVERY kOF'-Zr1IC0'TI1VE'~ PERIMEiJTAL---CI GARETTES- ~.._:, _ =t ~- -«- 1 2 1-- c r i , r .-t t . F . L F= ; , T t t -1 463 ..__ t . t t rso ^ ~ ~ 4 P'u'F,F I!vU!M 13ER

Text Control

Highlight Text:

OCR Text Alignment:

Image Control

Image Rotation:

Image Size: