Tobacco Documents Online

FIGLrRE 2 Page 1 Purge and Trap GC-HS-DS of Long Sectlou from FAVOE Long Section ** GC CONDITIONS FOR RUN, 183 Date: 3/ 1/1984 3:88 PM Thursda~ XFER LINE SOURCE RNRLYZER CURRENT TEMPERATURES (deg.) 188 148 188 Procedure 8 ** ******************************************************************************** CRPILLRRY CONDITIONS: Cap Inject Temp. = -4B deg. Time be?ore ramp =11.9 min. Ramp Rate = maximum Purge 077 Time =11,8 min. FLON RATE = 1,5 el./min. TEMPI TIMEI RATE TEMP2 TIME2 IHJ.PORT MRX.OVEN SOLVENT RUN TIME Deg. min. Deg/min. Deg. Min. Deg. Deg. Bin. min. 58 8.B 3.8 228 26.8 226 226 12.0 80.8 EI RUTOTUNE FILE 3 dated 3/ 1/1984 DFTPP NORMALIZED OPTICS TUNED RT MRSS 582 MS PERK DETECT THRESHOLD = 25.8 linear Counts SRMPLES PER .1RMU = 2 SCRH SPEED = 690 amu/sec ELECTRON MULTIPLIER - 1488 VOLTS GC PERK DETECT THRESHOLD = 588 TRIGGERED ON TOTRL RDUNDRNCE DETWEEH SCRN DELRY= e.e80 seconds when saving all spectra. ONLY STRIPPED SPECTRR RECORDED IN PERKFINDER MODE. DEGIN RUN IN PEAKFINDER MODE. 3 slave drives start|ng drive # 1,788 Last spectrum recorded on slaue(ID# 2)= 1682, to~al remaining = 617 Next spectrum recorded on slaue(ID# 2)= 1683. Last spectrum recorded on Baster (ID # 2>= 5~ ~otal remaining = 2214. Next spectrum recorded on Baster (ID # 2)= 1. COLUMN: J & W CRRDONRX 28M #88844 8.328 mm I.D. * 54 m SRMPLE: LONG CELLULOSE ROD FROM BOB JOHNSONS SRMPLE OPERRTOR:EDR TOTR~ RBUHDRNCE FROM 29 TO 329 amu ION 84.8 Full Scale= 8888 Full Scale= 288 RT SCRH DP BP REUND t,,rl ca ¢J Go W_________..

i Limonene Aliphatic Hydrocarbon Styrene A Picoline A Picoline ~ine Tridecane . ..% Page 2 Figure 2 17. 101603 75.1 172 19.821604 79.2 38 21.461605 68.2 199 .21.881606 57.1 78 22.681687 184.2 834 22.781608 184.2 448 22.921609 104.2 356 23.841610 184.3 832 23,181611 184.2 274 23.801612 104.2 136 23,421613 104.2 137 24.081614 93.2 41 24.221615 45.1 180 24.501616 93.2 55 24.601617 93.2 152 24.841618 43.2 18821 25.441619 48.2 172 ~=~ 0 0 0 t~

¢.. ..° ~t" 2, 5-Dimethylpyrazine 2,6-Dimethylpyrazine idine 39, 41, 82, 55, 54 ~2, 3-Dimethylpyrazine ~ 2-Cyclopenten-l-one ~Diacet~,vl ~A 2°r_~leyclopenten-l-one ¢is-3-Hexen-l-ol n Ethyl Pyridine +? A Hy rocarbon A Silyl Cpd. ~ , 94, 106, 40, 121, 38, 39, 81 n~Tetradecane ~A Silyl Cpd. ~Similar to Furfural~°mplex Acet±c Acid Dimethyl 2-Cyclop, and Tetra Methyl Py~ Furfural ~Menthone ~3 or 4 - Vinylpyridine ~_~2-Acetylfuran ~6, 115, 80, 109, ll0-~art Indene ~Mixture 57, 55, 56 Benzaldehyde ~Calumn or Septa Bleed CTent. A C4-Alkylcyclopenten-l-one C > Page 3 - Figure 2 25.761628 42.2 129 2g.821621 42,2 252 26.241622 187,2 154 26.461623 43.2 9? 26.781624 39.2 128 26.881625 39.2 463 27.221626 432 2109 27.~81629 57.1 576 ~7.941638 92.2 I~3 28.341631 121.3 144 28.681632 43.2 323 28.881633 207.3 1492 29.661636 135.1 66 29,881637 121.3 49 38.861638 95.1 315 38.481639 43.2 4211 Iten-l-one 38.821648 67.1 186 Lzine 31.221641 43.2 4859 31.421642 96.2 2161 31.721643 112.3 149 21.881644 185.2 514 32.881645 95.2 347 32.381646 115.3 51 32.681647 54.1 48 33.621655 67.1 2322 ~3.941656 186.2 264 34.16165? 43.2 367 ~:~ 2~?:~ 1~ 35.141668 41.2 335 &a o o o o

°. °. °.. k "T~rpene Alcohol -- 109,110.5" ~ 43, 39, 124" Protoanemonln Mixture 131, 57, 132, 43, 42, 121-Mixture i, (?)-Dimethylpyrrole or )lex-A Mixture ,124,39,41,109,67,81 110,81,53,67,39,45,54,107 Similar to Geranoil ~, 71, 41, 69, 55 , 98, 144-'~ Met~.l D~" -" 128~ 133, 144, 124~l~ap~tha~ 68, 39, 129, 43, 124-Complex n-Heptadecane Naphthalene • Solanone 134 ? Some Formamide 45, 57, 41, 44, 60 Page 4-Figure 2 Check 5-Met~y'f ~ur~&ril 36.361664 42.2 444 36.721665 82.1 134 37.061666 131.2 81 37.18166? 94.2 99 37.581668 122.3 57 Complex 37.861669 42.2 166 38.001670 110.3 91 38.401671 43.2 88 38.681672 69.2 1628 ~9.881676 41.2 114 41.241677 57.1 117 41,481678 41.2 59 41.661679 129.1 48 42.161680 68.1 142 42.381681 79.2 34 42.601682 43.2 232 42.761683 128.2 606 43.021684 43.2 130 43.121685 135.1 120 43.241686 119.3 79 43.601687 45.1 95 44.501698 44.1 76 44,041691 45.1 30 45.021692 44.2 100 45.501693 45.1 294 ka &o -4 H=

112, 81, 53, 55 117, 44, 116, 90 Complex Phenol and some Cresol Cpd. Triacetin Page 5-Figure 2 46,201694 44.2 A6.901695 57.2 157 50,521710 43,2 76 51.081711 156.2 32 52.081712 94.2 672 52.701713 207.3 168 52.801714 207.3 277 55.061715 43.2 21605 i i!II# II!, 55.721723 43.2 1568 55.901724 43,2 224

~2r Phenolic 43, 103, 121, 31, 41 ~-Nicotyrine TEGDA Page 6 Figure 2 .56.881737 43,2 57.801738 43.2 57.241739 43.2 58.361740 118.2 59.281741 121.3 59.441742 43.2 62.381743 158.2 ~3.901744 43.2 368 512 360 958 236 202 297 411

° 68.161745 165.2 Page 7 Figure 2 126 Gq

.1~rge and Trap GC-MS-DS of Plug Wrap from FAVOR ** GC CONDITIONS FOR RUN 181 Date: 3/ 1/1984 18:50 AM XFER LINE SOURCE RNRLYZER CURRENT TEMPERRTURES (des.) 180 148 180 Thursday ~age Plug Wrap Procedure e ~ ******************************************************************************** CRPILLRRY CONDITIONS: Cap Inject Temp. = -4e deg. Ttae be¢ore ramp =11.0 mtn. Ramp Rate m maximum Purge 0¢¢ Time =11.0 min, FLOM RRTE = 1.5 ml,/mtn, TEMP1 TIMEI RRTE TEMP2 TIME2 IHJ.PORT MRX,OVEN SOLVENT RUN TIME DeS. min. Deg/mtn. DeS. Min. DeS. DeS, min. min. 58 0.0 3.0 220 26.0 226 226 12.0 88.8 EI RUTOTUNE FILE 3 dated 3/ 1/1984 DFTPP NORMRLIZED OPTICS TUNED RT MRSS 502 MS PERK DETECT THRESHOLD - 25.0 linear counts SRMPLES PER .1RMU = 2 SCRN SPEED = 698 amu/se¢ ELECTRON MULTIPLIER = 1400 VOLTS GC PERK DETECT THRESHOLD = 580 TRIGGERED OH TOTRL RBUNDRHCE BETWEEN SCRN DELRY = 0,000 seconds when saving all spectra. ONLY STRIPPED SPECTRR RECORDED IN PERKFINDER MODE. BEGIN RUN IN PERKFINDER MODE, 3 slave drives starting drive # Im700 Last spectrum recorded on slave(ID# 2)= 1481, total remaining = 738 Next spectrum recorded on slave(ZD# 2)= 1482. Last spectrum recorded on master (ID # 2>= Next spectrum recorded on master (ID # 2)= 5~ to¢al remaining = 2214. 1. COLUMN: SRMPLE: OPERRTOR:eda TOTRL RBUNDRNCE FROM Full Scale- 8000 J & W CRRDOWRX 20M #08044 0.320 mm I.D. * 54 m BOB JOHNSON'S PLUG WRRP PLUS ????? 29 TO 329 amu ION 84.0 Full Scaler 200 RT SCRH BP BP RBUHD C . C¢ -3

T Probably A Silyl Cpd. Aliphatic Hydrocarbon Silyl Cpd. Dodacane Page 2 Figure 3 17.881482 75.1 19.081483 57.1 21.141484 147.1 21.861485 43.2 ~2.901486 184.2 23,021487 184.2 23.141488 184.2 23.261469 104.2 23.681498 57.1 24.641491 56.1 24.861492 43.2 84 103 8? 388 482 133 102 52 106 60 722 ka

T ? 2, 6 - Dimethylpyrazlne? Possibly part 2-methyl-2-hepten-6-one Diacetone Alcohol Part Aliphatic Hydrocarbon Silyl Cpd. Silyl Cpd. ~Hydr°carb°;SilyI • Cpd. E-Tetra Decane Silyl Cpd. tent. ~-Pentylbenene Hydrocarbon Furfural Tent. 4 or 3 - Vinylpyridine 135, 73, 207, 136, 269 ? Complex Hydrocarbon Type Weak 299, > 26.061494 42.2 26,421495 43.2 ~6.961496 39.2 27.221497 43.2 27.621498 57.1 ~7.941499 73.1 28.361500 237.2 20,541501 43.2 28.861582 287.3 29.441503 43.2 29.621504 135.1 29.801505 91.2 30.541586 43.2 31.161507 43.2 31.381588 95.1 31.841589 185.2 32.681518 135.1 33.681518 67. I 33.841519 43.2 ~4.881522 57.2 35.121523 39.2 Page 3 Figure 3 88 104 62 2634 96 91 83 301 1792 197 76 145 1198 158 219 94 53 284 61 4~ 58 49 Ul ka Ca