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il P RESPIRATOR SELECTION (UPPER LIMIT DEVICES PERMITTED): i-! I GH LEVELS - GAS MASK WITH AN ORGANIC VAPOR CANISTER (CHIN•-STYLE OR FRONTOR BACK-MOUNTED CANISTER) - SELF-CONTAINED BREATHING APPARATUS FIREFIGHTING - SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE-PIECE OF'ERATED IN PRESSURE-DEMAND OR POSITIVE-PRESSURE MODE. MS MEDICAL SURVEILLANCE: NO NIOSH/OSHA DATA; ADVISE: EKG RECOMMENDED IF EMPLOYEE TO WEAR FULL-FACE RESPIRATOR. GENERAL MEDICAL HISTORY. 40CFR717 RECORDS AND REPORTS OF ALLEGATIONS THAT CHEMICAL SUBSTANCES CAUSE SIGNIFICANT ADVERSE REACTIONS TO HEALTH OR THE ENVIRONMENT TOXIC SUBSTANCES CONTROL ACT (TSCA) SECTION 8(C) RULE REQUIRES MANUFACTURERS AND CERTAIN PROCESSORS OF CHEMICAL SUBSTANCES AND MIXTURES TO K.EEF' RECORDS OF SIGNIFICANT ADVERSE REACTIONS TO EMPLOYEE HEALTH FOR =0 YEARS 48FR38187 08/22/83 48FR7,9?25 o8/.'_•.tJ/81 (EFFECTIVE DATE CORRECTION). PHYSICIAN EXAMINATION INDUSTRIAL EXPOSURE HISTORY. FRE-PLACEMENT AND ANNUAL EXAMS. MEDICAL WARNING FOR REFUSAL OF MEDICAL EXAMINATION. RE ROUTE OF ENTRY: INHALATION. INrESTION, Sk::IN OR EYE CONTACT. TO TARGET ORGANS: EYES. SKIN. CENTRAL NERVOUS SYSTEM.• GASTROINTESTINAL. KIDNEYS.

WASTE DISPOSAL. (1 OF 1) THIS MATERIAL NOT LISTED AS HAZAFDOUS SUBSTANCE, AS DEFINED IN SE:CT I 1 i? 1( 14 ) OF THE COMPREHENS I VE ENV I FONMENTAL EESF'ONSE, COMF'ENSAT I ON, AL I AEj I L I TY ACT MORE OF THE FOLLOWING: * FEDERAL SECTION 7,11 (E•1) (2) (A) * SOLID * CLEAN ( CERCLA ) OF 1980, FPURSUANT TO ONE OR WATER F'OLLUT I ON CONTROL ACT ( FWF'CA ) WASTE DISPOSAL ACT SECTION 3001 WATER ACT (CWA) SECTION ?07 (A) * CLEAN A I F; ACT ( CAA ) SECT I ON 112 * TOXIC SUBSTANCES CONTROL ACT (TSCA) SECTION u NT ? * COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILIT ACT (CERCLA) SECTION 102. NOTES: REACTS WITH LIGHT METALS, FORMING FLAMMABLE HYDROGEN GAS. ATTACKS MANY PLASTICS. C+C FaRASRAFH SENTENCE NS-WORD F; N (1) ~ 2

1 AN ACCESS I ON NUMBER: 2192. 8508. CN CHEMICAL NAME: PROPYLENE GLYCOL. SY SYNONYMS: 1,2-PROPANEDIOL. METHYL GLYCOL. 1,2-PROPYLENE GLYCOL. MONOPROF'YLENE GLYCOL. 1,2-DIHYDROXYPROPANE. PG 12. METHYLETHYLENE GLYCOL. PROF'ANE-1,2-DIOL. ALF'HA-F'ROPYLENEGLYCOL. TRIMETHYL GLYCOL. SIRLENE. METHYL ETHYLENE GLYCOL. RN CAS NUMBER: 57-JJ-6. REG. TOXIC NUMBER: TY200000s>. CHEMICAL 1=0RMULA: C3H802. PD PHYSICAL DESCRIPTION: COLORLESS, ALMOST ODORLESS, SLIGHTLY VISCOUS LIQUID SLIGHTLY ACRID TASTE. MOL WT: BOILING PT: SOLUBI L I TY: 76.11 :'72 F SOLUBLE FLASH PT: 215-225 F (OC) VAPOR F'RES: 0.13 MM MELT PT: -24 F UEL IN AIR: 12.5% LEL IN AIR: 2.6% MEC IN AIR: 700 F SPEC GRAV I TY: 1.0361 VAPOR DENSITY: ODOR THRESHOLD: 2.52 OCTANOL/WATER CO-EFFICIENT: -1. 41 /-0. 30 (CALC. ) . I

CL CLOTHING: EMPLOYERS SHALL PROVIDE AND ENSURE THAT EMPLOYEES U SE AF'FROPRIATE PROTECT I VE CLOTH I NG AND EQU I F'MENT NECES aARY TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. FACE SHIELDS SHALL COMPLY WITH 29CFR191(). 1v3(A) (2) , (A)(4), (A)(5), AND (A)(6). EMPLOYERS SHALL ENSURE THAT CLOTHING CONTAMINATED WITH THIS SUBSTANCE IS PLACED IN CLOSED CONTAINERS FOR STORAGE UNTIL IT CAN BE DISCARDED OR UNTIL THE EMPLOYER PROVIDES FOR THE REMOVAL OF THE CONTAMINANT FROM THE CLOTHING. IF THE CLOTHING IS TO BE LAUNDERED OR OTHERWISE CLEANED TO REMOVE THE CONTAMINANT, THE EMPLOYER SHALL INFORM THE PERSON PERFORMING THE CLEANING OF THE HAZARDOUS PROPERTIES OF THE SUBSTANCE. _ ACGIH "GUIDELINES FOR SELECTION OF CHEMICAL F'ROTECTIVE CLOTHING" INDICATES THE FOLLOWING MATERIALS AND PROTECTIVE RATINGS BY INDEPENDENT VENDORS AGAINST ALIF'HATIC AND ALICYCLIC HYDROCARBONS: EXCELLENT/GOOD: NEOPRENE NITRILE RUBBER POLYURETHANE POLYVINYL ALCOHOL VITON GOOD/FAIR: CHLORINATED POLYETHYLENE FAIR/POOR: BUTYL RUBBER NATURAL RUBBER NEOPRENE/NATURAL RUBBER POLYVINYL CHLORIDE FAIR/GOOD: NEOPRENE/STYRENE-BUTADIENE RUBBER NITRILE/POLYVINYL CHLORIDE POLYETHYLENE STYRENE-F{UTADIENE RUBBER. WEAR EYE PROTECTION TO PREVENT: NONE REQUIRED. EMPLOYEE SHOULD WASH: EMPLOYERS SHALL ENSURE THAT EMPLOYEES WHOSE SKIN BECOMES CONTAMINATED WITH THIS SUBSTANCE F'ROMF'TL"Y WASH OR SHOWER TO REMOVE ANY CONTAMINANT FROM THE SKIN. EMPLOYERS SHALL ENSURE THAT EMPLOYEES WHO HANDLE TH I S SUBSTANCE WASH THE I R HANDS THOROUGHLY BEFORE EAT I NG , SMOKI NG, OR US I NG TO I LET FACILITIES. WORK CLOTHING SHOULD BE CHANGED DAILY: NOT REQUIRED. REMOVE CLOTHING: EMPLOYERS SHALL ENSURE THAT NON-IMPERVIOUS CLOTHING WHICH BECOMES CONTAMINATED WITH THIS SUBSTANCE BE REMOVED PROMPTLY AND NOT REWORN UNTIL THE SUBSTANCE IS REMOVED FROM THE CLOTHING. THE FOLLOWI NG EnU I F'MENT SHOULD BE AVA I LABLE : NONE REQUIRED. C7~ Cd GO ( ' N ~ ~

:L PERMISSABLE EXROSURE: NONE ESTABLISHED TERATOGENIC DATA (RTEC) MUTAGENIC DATA (RTEC) CERCLA HAZARD RATINGS - TOXICITY 0 - IGNITABILITY 1- REACTIVITY 0 - F'ERSISTENCE U TOXICOLOGY: INDUSTRIAL EXPOSURE TO FRORYLENE GLYCOL IS MAINLY FROM SKIN CONTACT OR INHALATION OF VAPORS OR MISTS FROM HEATED LIQUID. THE HEALTH HAZARD IS NEGLIGIBLE FOR NORMAL HANDLING. THE FDA ALLOWS THE USE OF PROPYLENE GLYCOL IN FOOD AND COSMETICS. INGESTION OF MASSIVE DOSES WILL CAUSE GASTROINTESTINAL UPSET AND UNCONSCIOUSNESS. ALCOHOLIC INTAKE ENHANCES THE TOXIC EFFECT. EYE CONTACT IS NOT INJURIOUS, BUT MAY CAUSE LACRIMATION, STINGING, OF BLEPHAROSF'ASM. SKIN CONTACT CAN PRODUCE PRIMARY IRRITATION, BUT NOT SENSITIZATION. ORL-CHD TDLO: 79 GM/F.:G/56 Wk:-INTERMITTENT ORL-RAT LD50: 20 GM/KG ORL-MUS LD50: 24 GM/KG ORL-DOG LD50: 22 GM/KG ORL-RBT LDLO: 20 GM/KG ORL-GPG LD50: 19 GM/KG SKN-RBT LDS0: 2ogcjo MG/k;G OSHA STANDARD 29CFR1910.1200 HAZARD COMMUNICATION REQUIRES CHEMICAL MANUFACTURERS AND IMPORTERS TO ASSESS THE HAZARDS OF CHEMICALS WHICH THEY PRODUCE OR I MF'ORT , AND ALL EMPLOYERS HAV I NG 4+JORF=:F'LACES I N THE MANUFACTURING DIVISION, STANDARD INDUSTRIAL CLASSIFICATION CODES 2.0 THROUGH 39, TO PROVIDE INFORMATION TO THEIR EMPLOYEES CONCERNING HAZARDOUS CHEMICALS BY MEANS OF HAZARD COMMUNICATION PROGRAM INCLUDING LABELS, MATERIAL SAFETY DATA SHEETS, TRAINING, AND ACCESS TO WRITTEN RECORDS 48FR5''280 11/20/83 FOLLOWING OSHA STANDARDS AF'F'L I CABLE TO SUBSTANCES L I STED ?9CFF;191 0, OTHERW I SE ADV I SE. DANGEROUS EXPOSURE: NONE SPECIFIED COLORLESS, ALMOST ODORLESS, SL. IC INCOMPATIBILITIES: STRONG OXIDIZERS. METALS. MAY FORM EXPLOSIVE PEROXIDE(S). VAPOR-AIR MIXTURES ARE EXF'LOSIVE ABOVE FLASH FOINT! .

(12 OF 12) EPISODE REPORT IN DEVELOPMENT/PROGRESS CLEAN WATER ACT (CWA). CT DOCUMENTS SAVED FOR EMPLOYEE RECORDS: NO FEDERAL AGENCY REQUIREMENT, BUT DUE TO HAZARDOUS NATURE OF SUBSTANCE, ADVISE FOLLOWING: HEALTH STATUS CLASSIFICATION. OSHA RESPIRATOR CERTIFICATION 29CFR1910.134. DEPARTMENT OF TRANSPORTATION IF OPERATES HEAVY EQUIPMENT. EMPLOYEE HAZARDOUS MATERIALS EDUCATION RECEIPT. EMPLOYEE MEDICAL RECORDS RECEIPT TOXIC SUBSTANCES CONTROL ACT (TSCA) SECTION 8(C) RULE REQUIRES MANUFACTURERS AND CERTAIN PROCESSORS OF CHEMICAL SUBSTANCES AND MIXTURES TO KEEP RECORDS OF SIGNIFICANT ADVERSE REACTIONS TO EMPLOYEE HEALTH FOR 30 YEARS. CONTACT: JACK P. MCCAFTHY, OFF I CE OF TOX I C SUBSTANCES, EPA ( 80()) 424-1404. 48FR'8178 S/22/S3. MED I CAL WARN I NG REQU I F;ED FOR MED I CAL EX AM REFUSAL S I GNED BY EMPLOYEE. LS LEAKS, SPILLS, FIRE AND EVACUATION PROCEDURES. DEF'AF':TMENT OF TRANSPORTATION HAZARD CLASS 49Cf=R172,.1o1 HAZARDOUS MATERIALS TABLE. NOT LISTED. INTERGOVERNMENTAL MARITIME ORGANIZATION HAZARD CLASS 49CFP172').10C OPTIONAL HAZARDOUS MATERIALS TABLE. NOT LISTED. L I STED BY U. S. COAST GUARD UNDER CARGO COMPAT I BI L I TY GROUP ALCOHOLSGLYCOLS, INCOMPATIBLE WITH THE FOLLOWING MATERIALS: SULFURIC ACID, NITRIC ACID, CAUSTICS,'ALIPHATIC AMINES, ISOCYANATES.

r{ S REGULATORY STATUS. (1 OF 12) OSHA STANDARD 29CFR191 0. 1 20U HAZARD COMMUN I CAT I ON REL?U I FtES CHEM I CAL MANUFACTURERS AND IMPORTERS TO ASSESS THE HAZARDS OF CHEMICALS WHICH THEY PRODUCE OR IMPORT, AND ALL EMPLOYERS HAVING WORKPLACES IN THE MANUFACTURING DIVISION, STANDARD INDUSTRIAL CLASSIFICATION CODES 20 THROUGH 39, TO PROVIDE INFORMATION TO THEIR EMPLOYEES CONCERNING HAZARDOUS CHEMICALS BY MEANS OF HAZARD COMMUNICATION PROGRAM INCLUDING LABELS, MATERIAL SAFETY DATA SHEETS, TRAINING, AND ACCESS TO WRITTEN RECORDS 48FR5•=y28() 11/25/8.3 FOLLOWING OSHA STANDARDS APF•L I CABLE TO SUBSTANCES L I STED 29CFR 191 U, OTHEE.W I SE ADV I SE . (2 OF 12) OSHA STANDARD 29CFR 191 0. 94 VENT I LAT I ON OSHA STANDARD 29CFF":191 0. 1 Ly4 RESPIRATORY PROTECTION. (.? OF 12) OSHA STANDARD 29CFR1910.20 ACCESS TO EMPLOYEE EXPOSURE AND MEDICAL RECORDS. (4 OF 12) OSHA STANDARD 29CFF:1910.132 PERSONAL PROTECTIVE EQUIPMENT. (5 OF 12) OSHA STANDARD 29CFR1910.141 SANITATION. (6 OF 12) OSHA STANDARD 29CFR1910.151 MEDICAL SERVICES AND FIRST AID. (7 OF 12) OSHA STANDARD 29CFF;191U.1=.' EYE AND FACE PFOTECTION. (8 OF 12) 40CFR717 RECORDS AND REPORTS OF ALLEGATIONS THAT CHEMICAL SUBSTANCES CAUSE SIGNIFICANT ADVERSE REACTIONS TO HEALTH OR THE ENVIRONMENT RE[!U I RES MANUFACTURERS AND LERTA I N PROCESSORS OF CHEM I CAL SUBSTANCES AND MIXTURES TO KEEP RECORDS OF SIGNIFICANT ADVERSE REACTIONS TO HEALTH OR THE ENVIRONMENT ALLEGED TO HAVE BEEN CAUSED BY A SUBSTANCE OR MIXTURE. EPA MAY INSPECT AND REQUIRE REPORTING OF SUCH RECORDS. 48FR38178 08/222/8-). (9 OF 12) SUBSTANCE LISTED TOXIC SUBSTANCES CONTROL ACT INVENTORY. ( ),o OF 12) TECHNICAL ASSISTANCE DATA COMPLETED/PUBLISHED CLEAN WATER ACT (CWA) SECTION 311. (11 OF 12)) REGULATION PROMULGATED RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40CFR2b0. 886981`7"1

SF-. SYMPTOMS: SKIN, COVERING OF BODY (SCif174) ; IRRITATION, EXTREME REACTION TO A CONDITION (SC0090). EYE, ORGAN OF SIGHT (SCO170) ; IRRITATION, EXTREME REACTION TO A CONDITION (SCO090). LACRIMATION, DISCHARGE OF TEARS (SC0~096). HYPOGLYCEMIA, ABNORMALLY LOW BLOOD SUGAR ( SCO._ 21 ) . CENTRAL NERVOUS SYSTEM, F'EFtTA I N I NG TO NEURAL BODY SYSTEM ( SCO0E8 ); DEPRESSION, DECREASE IN ACTIVITY/FUNCTION (SCV043). MUCOUS MEMBRANE, MEMBRANE LINING PASSAGES/CAVITIES (SCO109) ; IRRITATION, EXTREME REACTION TO A CONDITION (SCt7090). NARCOSIS, STUPOR OR SLEEP DUE TO NARCOTIC (SCO11:1). HEADACHE, PAIN IN HEAD OR CFAN I UM AREA ( SC00a75 ). NAUSEA, S I CF.:NESS AT THE STOMACH ( SCO1 15 ). VISUAL DISTURBANCE, UF'SET IN SIGHT (SC01b5). VOMITING, PERTAINING TO NAUSEA ( SCO1 F 5). ABDOMINAL, RELATING TO THE ABDOMEN (SCOtua1 ); G SF'ASM , CONVULS I VE MUSCULAR CONTtiACT I ON ( SCO1 O:' ). E::I DNEY DAMAGE, I NJ URY TO THE KI DNEY (SC0220); IN EXPERIMENTAL ANIMALS, (SC0212). REPRODUCTIVE EFFECTS, BIRTH DEFECTS (SC0281); IN EXPERIMENTAL ANIMALS, (SC~'Y.?1?) . FA FIRST AID. (1 OF 4) IF THIS CHEMICAL GETS INTO THE EYES, IMMEDIATELY WASH THE EYES WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING THE LOWER AND UPPER LIDS. GET MEDICAL ATTENTION IMMEDIATELY. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKI NG W I TH TH I S CHEM I CAL . (i OF 4) IF THIS CHEMICAL GETS ON THE SKIN, IMMEDIATELY WASH CONTAMINATED SKI N W I TH SOAP OR M I LD DETERGENT & WATER. I F TH I S CHEM I CAL SOAKS CLOTHING, IMMEDIATELY REMOVE CLOTHING & WASH SKIN WITH SOAP OR MILD DETERGENT & WATER. GET MEDICAL ATTENTION PROMPTLY. (3 OF 4) IF A PERSON BREATHES IN LARGE AMOUNTS OF THIS CHEMICAL, MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IF BREATHING HAS STOPPED PERFORM AFiT I F I C I AL F;ESF I FAT I ON. KEEP THE AFFECTED PERSON WARM AND AT REST. GET MEDICAL ATTENTION AS SOON AS POSSIBLE. DT (4 OF 4) WHEN THIS CHEMICAL HAS BEEN SWALLOWED AND PERSON IS CONSCIOUS, IMMEDIATELY GIVE PERSON LARGE QUANTITIES OF WATER. AFTER WATER HAS BEEN SWALLOWED, TRY TO GET THE PERSON TO VOM.IT BY HAVING HIM TOUCH THE BACK OF HIS THROAT WITH HIS FINGER. DO NOT MAKE AN UNCONSCIOUS PERSON VOMIT. GET MEDICAL ATTENTION IMMEDIATELY. OD ~ SPECIAL DIAGNOSTIC TESTS AND INDEXES OF EXPOSURE: (~ LIVER F'(";OFILE BLOOD TESTS. ~ ~ ~