Health Canada
Document 10055284
Fields
- Notes
Selected on visit 1 (May 1999)
- Site
- Guildford
Document Images
/
Mr. W.H. Deines P.D. Case
Or. R.R. Baker
PDC/AIW146H i June 1987
CAPRI STUDY - OBJECTIVE AND SUBJECTIVE MEASURES
1) Sidestream Objective Measurements
a)
b)
c)
d}
e)
To be done both puffed and smouldered
Analyses - Sidestream..- ~i~I
(
TNAJ
CO J
CO2 ~/
gotal Hydrgj;arbons~-~
henol s
ol atlle Al dehjydes
ormal dehyde~
~H CrOl ei n
CN
~nia
ticulate Phase Scan (if available)
samlnes (Volatile and Tobacco Specific)
al Oenslty
Analyses - Mainstream
v~Nll the above, plus: Itric Oxide
~.~plllary Vapour Phase Scan or
~pPartked Column Yapour Phose Scan
iculate Phase Scan (if available)._
~oTE. c~cAbL)~,7~ ~Jol-
#V/h~
Physical Testing, etc.
~per Analyses
/Physical Measurements etc'~J/
%/" Physical Testing (SBR, Expanded tobacco,
Mainstream Analyses TPH, PI~#NF, TNA, CO, NO
Tobacco Analyses: Nitrate, blend, ash
Co~ustton Measures
/
Puffing and Smoulder Burn~el~peratures~
Burn Rate Monitor Data ~/
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2) Environmental/Chamber Room Measures:
Particulate Matter
Nicotine
CO
CO2
Total Hydrocarbons
Methane
Non-Methane Hydrocarbons
Oxides of Nitrogen
Nitric Oxide
To be carried out puffed and one number of cigarettes under one set
of environmental conditions,
3}
Subjective Studies
a) Boot, studies (to include haze) using a fixed length of v/~-~--)
tobacco rod being consumed. Capri versus other 3 only.
Black Box studies visibility of Capri versus other/
b)
$idestream
3 only.
/
c) Environmental Room/Chamber smoulder studies. Capri versus ~//
other 3 only.
d)
Fabric Box technique sensory testing Capri against other 3. )~Gi-~o~JF-.
but allowing for cigarettes to all smoulder a set length of
)
~1 me.
• ;
Other
Establish product pluses - can slims be patented from a total stdestream
reduction standpoint.
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PUFFED AND SMOULDERED SIDESTREAM YIELDS
PRODUCT
VIRGINIA SLIMS
= ~-,. ..
MARLBORO BOX
DQRAL L[GHTS
CAPRI
SIOESTREAH DATA PUFFED
H9 CIg-1
PHWNF TNA
30.1 4.09
26.4 3.61
21.2 2.52
20.3 2,64
PUFF
" HO. ]IHE
CO co2 THC ALIGHT
Hlns
50 391 28.0 10.3 11,1
42 349 25.0 9.0 10.7 26.4
48 335 20.2 6.8 8.2 19.5
44 266 18.9 9.3 10.8
STDESTREAH DATA SHOULDERED
H9 C19-1
_L
PHWNF TNA CO CO2
r, . ,i
THC
28.2 4.13 59 495 34,8
4.19 57 510 33.6
2.50 47 424 27.4
20.8 2.99 43 313 23.6
% INCREASE/DECREASE
SMOULDERED RELATTVE
TO PUFFED
,_.,,
PHNNF TNA CO CO2/THC
1 18 35 24
O 16 36 46 34
-8 1 2 27 36
" L' ' '~ '
2 13 -2 18 24
Note 1:
Note 2:
Note 3:
Increase - smoulder-puffed
puffed x 100
-re means that puffed yteld ts higher than smouldered
1CII = Total t~drocarbon Content oF stdestream vapour phase expressed as m9 c|g-1 of methane
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FACSIMILE MESSAGE FROM
SOUTHAMPTON 780332
(AREA CODE [0] 703)
f,..
DATE :.
TO THE
FACS It{ I LE OPER ATOR
PLEASE PASS THE FOLLOWING
TO /-.~~
WITH COPIES ALSO TO
PROt! J
PAGE/PAGES
FOR
IF TfIERE IS ANY PROBLEH WITH TIIE COPY PLEASE TELEPIIONE
SOUTIIAMPTON 782111 AND ASK FOR E.~{TEN~TON 2428 OR 2426
§LgZ~;§O01
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TABLE 1
SIDESTREAH YIELDS (I~ASUItEO AHO CALCULATED.)
Product
Hmne
Virginia Slims
Camel
~nson & Hedges
A279
~rlboro Lights
~rlt
Vanta9e
Dar.cl ay
• rlboro Box
Dora1 Lights
Caprt
....... CaiculaLed Sidestream Yield
Sidestream ~lelds mg Per Gram Dry ~terial
(m9 clg-1) (Tobacco and Htcottne)
. ,.. ,- .
Puff
Pt4~F THA CO CO2 No. PHI#IF TNA
30.1 4.09 50.2 391 10.3 53.3 338
29.6 4.34 !54.7 447 8.5 48.9 377
o
29.3 5.30 55.5 428 9.7 46.2 P338
28.8 5.08 75.9 521 9.4 42.8 i328
28.6 3.9L 49.7 387 9.0 51.L 343
28.3 4.17 50.8 355 8.0 53.5 353
28.24.1351.0346 7.450.9352
27.3 4.37 5,._4 4.~ 10.0 r48.7 352
~X~f ~~ 90 438 295
212 252478 335 ~8 !431 ~,
203 264437 226 93 553 325
CO COz
76.0 592
91,6 633
75.7 583
95.7 557
76.1 592
81.7 588
79,6 540
78.9 542
51.7 508
83.1 583
103.1 527
HoLe: B~nson & Hed9es ~s a BAT (UKSE) Produced Product.
A279 is an Internal RADC Virginia Product.
In terms of P~F Capri ts the lowest product tested within
this series being 33% below Virginia slims.
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MAINSTREAM AND SIDESTREAM SMOKE PARTICULATE PHASE ANALYSIS OF
CAPRI.~ MARLBORO, VIRGINIA SL~MS AND DORAL" LIGHTS.
2--
OBJECTIVE.
The purpose of this investigation was to obtain a detailed
comparison of the composition of the particulate phase of both
mainstream smoke and sidestream smoke produced by Capri and three
other brands. This has been achieved by GC-MS analysis of
extracts of Cambridge filter pads used to collect mainstream and
sidestreamproducsdby smoking the cigarettes on a modified 20
port smoking engine.
METHOD OF ANALYSIS.
Mainstream and sidestream smoke were collected simultaneously
using a Filtrona smoking engine modified to allow the attachment
of fishtail chimneys. Smoking took place using standard regimes
and to a butt length of overtipping plus 3 mm. Three cigarettes
were smoked per port and each brand occupied 4 ports. Air was
drawn through the fishtail chimney at the standard rate of 2
litres per minute. After completion of smoking the pads were
extracted with 25 cc of propan-2-ol containing n-heptadecane as
internal standard by shaking for one hour.
The resulting extracts were analysed using a 60 metre 0.25 u ID
Supelcowax 10 capillary column directly interfaced to a
Hewlett-Packard mass selective detector. Data was primarily
processed by mass spectral identification of each peak, both to
highlight key compounds and to check whether any brand exhibited
any unique compounds. Some 26 chemicals were then used to
describe differences between brands. In each case an ion
characteristic of the particular compound was chosen, and it is
the peak area of this ion that is detailed in tables I, 2 and 3.
This procedure is necessary to ensure accurate assessment of the
concentration of each component by limiting the possibility of
chromatographic overlap. In the time available response factors
for each chemical were not acquired and so the data should be
used for brand comparison only.
INTERPRETATION OF THE DATA.
The following is a brief interpretation of the results presented
in tables i, 2 and 3.
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a) Mainstream smoke.
Data on nicotine and the phenols agrees in ranking terms with
with results of routine smoking. The less volatile aromatic
bases fall in line with this ranking of Marlboro highest,
Virginia Slims and Capri similar, and Dotal somewhat lower
(reflecting blend). However indole is found to be greater in
Capri than Virginia Slims. Of the more volatile bases Dorals are
similar to Marlboro in terms of pyridine with Capri over 50%
lower. Vinyl pyridine , however, ranks Capri second to Marlboro
with Virginia Slims and Dorals somewhat lower.
Phenol data shows Capri and Marlboro similar with Virginia Slims
around 50% lower and Dorals even lower. This trend is followed
in the case of ethyl phenol, but not for p-cresol where Capri and
Virginia Slims ere higher than Marlboro.
Neophytadiene follows the same ranking as nicotine ( Marlboro,
Virginia Slims, Capri then Doral }, but if you calculate the
ratio of nicotine to neophytadiene then Capri and Marlboro are
similar with Dotal and Virginia Slims significantly lower.
b) Sidestream smoke (puffed).
Unlike mainstream, the sidestream ranking for nicotine is
Virginia Slims the highest concentration followed by Marlboro,
Capri and finally Dotal. This trend is reflected in the less
volatile bases except in the case of myosamine where Capri is
significantly lowest of the four brands. Hexamethylenetetramine
as interesting with again Capri coming out lowest but with
Marlboro somewhat higher than Virginia Slims.
Phenol concentrations show Capri significantly lower than the
rest with Virginia Slims some 44% higher, though ethyl phenol
results have Virginia Slims lowest. P-cresol shows Marlboro and
Virginia Slims similar and around 39% higher in level than Capri,
with Dotal slightly lower again.
In every compound, apart from vinyl pyridine, Capri has a
significantly lower sidestream yield than Marlboro.
c~)Sidestream smoke (smouldered).
Comparisons between the data for puffed and smouldered sidestream
are interesting. Although trends are generally maintained yield
of bases are slighly higher in smoulder, and yields of acidic
compounds are slightly lower in smoulder as compared to puffed.
There is some odd data, such as ethyl phenol showing Virginia
Slims highest in line with phenol data (this may question_the
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puffed result), and vinyl pyrldine where Marlboro is highest in
smoulder. Hexamethylenetetramine in smoulder shows Virginia
Slims much the greatest though Capri maintains its position as
lowest yield.
The more volatile compound quantified in mainstream were not
observed in either sidestream analysis. This could be due to a
lower collection efficiency of the pad for the smaller sidestEeam
particles, to stripping of volatiles during the collect/on
period, or to a shaft of the chemicals from the particulate phase
to the vapour phase.
To summarise, the results use 26 chemical markers to put the
mainstream and sidestream smoke yields of Capri in perspective
with three other brands. For virtually every chemical Capri
shows a significantly lower yield than Marlboro both in
mainstream and sidestream smoke.
C J Proctor
BAT (UK&E) R&D Cen~e.
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~./.M]ORATORY SERVICES
Analytical Report
B.A.T |U.K.and Export} Limited
Ill=SEARCH • DEVELOPldENT CENTRE
SOU rHAMPT'ON ENGLANO
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No. AR. 87-20-01S
BRAND ANALYSIS:PROJECT 701.01.130
MRS. g. L. BRAYSHAW
MR.P.D.CASE
P/701.01.130
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BATCH
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BRAND
CAPRI
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Brand PM~F Nic CO CO2 ~ PN
Capri=e 20,3 2.9 40.9 261 21.1 9,6
R1 Sli~ Line 22.5 4.5 44.6 330 25.4 I0.I
Phillip Morris Lt ~m 25.0 3.7 42.6 368 aaa 8.5
R1 25.5 5.4 44.6 381 28.8 8.8
Peter S ~r~sant 27.2 3.5 51.8 392 aaa 8.5
West 27.6 3.8 53.7 410 aaa 8.3
HB ~ 27.7 3.8 51.1 404 aaa 8.8
Krone Lts 27.9 3.5 54.5 401 aaa 8.3
Erone 28;2 3.7 50.5 375 27.1 8.9
Ernte 23 28.2 3.3 55.1 417 aaa 8.8
R6 28.5 4.0 51,5 402 29.4 9.5
Camel 29.1 4.2 53.3 403 aaa 8.7
Kiln 29.5 3.7 57,5 408 aaa 9.3
Marlboro KS 30.6 4.5 52.4 411 aaa 8.5
Reval 32.9 3.9 60.4 416 aaa 9.0
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